The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Halogen oxides / Cl oxides / ClO / Cox(1979)_298K_277nm

DATAFILE: ClO_Cox(1979)_298K_277nm.txt
NAME: chlorine monoxide
FORMULA: ClO
AUTHOR(YEAR): Cox(1979)
T: 298K
λ: 277nm
BIBLIOGRAPHY: R.A. Cox, R.G. Derwent, A.E.E. Eggleton, and H.J. Reid, "Kinetics of chlorine oxide radicals using modulated photolysis. Part 2. - ClO and ClOO radical kinetics in the photolysis of Cl2 + O2 + N2 mixtures", J. Chem. Soc. Faraday Trans. I 75, 1648-1665 (1979); DOI: 10.1039/F19797501648
COMMENTS: The low intensity photolysis of Cl2 + O2 + N2 mixtures has been investigated using molecular modulation spectrometry to observe the radical species ClOO and ClO in the ultraviolet region

Band head of the (11-0) band of the of the A 2Π ← X 2Π transition

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