When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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DATAFILE: | ClO_Feierabend(2010)_218K_279.67nm(10,0).txt |
NAME: | chlorine monoxide |
FORMULA: | ClO |
AUTHOR(YEAR): | Feierabend(2010) |
T: | 218K |
λ: | 279.67nm(10,0) |
BIBLIOGRAPHY: |
K.J. Feierabend, D.K. Papanastasiou, and J.B. Burkholder, "ClO radical yields in the reaction of O(1D) with Cl2, HCl, chloromethanes, and chlorofluoromethanes",
J. Phys. Chem. A 114, 12052-12061 (2010);
DOI: 10.1021/jp107761t
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COMMENTS: | Differential absorption cross section Δσ at the (10,0) band head of the A 2Π ← X 2Π transition, i.e., the difference between the cross sections at the peak at 279.67nm and at the valley of the absorption spectrum at 279.56 nm, measured using cavity ring-down spectroscopy; Cl2O photolysis at 248 nm was the ClO source Measurements at temperatures between 200 and 296 K, a simulation of the relative temperature dependence of the ClO absorption cross sections (using available spectroscopic parameters) over the range 190-320 K, and an empirical polynomial fit of the temperature dependence yielded Δσ(T)/Δσ(296 K) = 3.5234 - 0.014486 T + 2.0137×10-5 T2 |
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