The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


Cross Sections

Quantum Yields


Contact, Imprint, Acknowledgements

When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Halogen oxides / Cl oxides / ClO / JPL-2002(2002)_298K_261.4nm(rec)

DATAFILE: ClO_JPL-2002(2002)_298K_261.4nm(rec).txt
NAME: chlorine monoxide
AUTHOR(YEAR): JPL-2002(2002)
T: 298K
λ: 261.4nm(rec)
BIBLIOGRAPHY: S.P. Sander, R.R. Friedl, D.M. Golden, M.J. Kurylo, R.E. Huie, V.L. Orkin, G.K. Moortgat, A.R. Ravishankara, C.E. Kolb, M.J. Molina, and B.J. Finlayson-Pitts, "Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies. Evaluation Number 14", JPL Publication 02-25, Jet Propulsion Laboratory, Pasadena, 2002;
COMMENTS: JPL-2002 recommendation for the peak cross section at the top of the continuum, adopting the earlier recommendation of

W.B. DeMore, S.P. Sander, D.M. Golden, R.F. Hampson, M.J. Kurylo, C.J. Howard, A.R. Ravishankara, C.E. Kolb, and M.J. Molina, "Chemical Kinetics and Photochemical Data for Use in Stratospheric Modeling. Evaluation Number 12", JPL Publication 97-4, Jet Propulsion Laboratory, Pasadena, 1997;,

which is based on the average of the studies of

H.S. Johnston, E.D. Morris, Jr., and J Van den Bogaerde, "Molecular modulation kinetic spectrometry. ClOO and ClO2 radicals in the photolysis of chlorine in oxygen," J. Am. Chem. Soc. 91, 7712-7727 (1969); DOI: 10.1021/ja50001a036 ,

J.L. Jourdain, G. Le Bras, G. Poulet, and J. Combourieu, "UV absorption spectrum of ClO (A 2Π -X 2Π) up to the (1, 0) band," Chem. Phys. Lett. 57, 109-112 (1978); DOI: 10.1016/0009-2614(78)80361-3 ,

S.P. Sander and R.R. Friedl, "Kinetics and product studies of the reaction ClO + BrO using flash photolysis - ultraviolet absorption," J. Phys. Chem. 93, 4764-4771 (1989); DOI: 10.1021/j100349a017 ,

M. Trolier, R.L. Mauldin, III, and A.R. Ravishankara, "Rate coefficient for the termolecular channel of the self-reaction of ClO," J. Phys. Chem. 94, 4896-4907 (1990)); DOI: 10.1021/j100375a027, and

F.-G. Simon, W. Schneider, G.K. Moortgat, and J.P. Burrows, "A study of the ClO absorption cross-section between 240 and 310 nm and the kinetics of the self-reaction at 300 K," J. Photochem. Photobiol. A: Chem. 55, 1-23 (1990); DOI: 10.1016/1010-6030(90)80014-O

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