When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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DATAFILE: | ClO_Park(1976)_200-2200K_253.7nm(fit).txt |
NAME: | chlorine monoxide |
FORMULA: | ClO |
AUTHOR(YEAR): | Park(1976) |
T: | 200-2200K |
λ: | 253.7nm(fit) |
BIBLIOGRAPHY: |
C. Park, "Rates of reactions ClO + ClO → Cl2 + O2 and ClO + O → Cl + O2 at elevated temperatures",
J. Phys. Chem. 80, 565-571 (1976);
DOI: 10.1021/j100547a002
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COMMENTS: | Fit of the measured absorption cross sections from shock-tube experiments (1660-2122 K) together with the room temperature value of
H.S. Johnston, E.D. Morris, Jr., and J Van den Bogaerde, "Molecular modulation kinetic spectrometry. ClOO and ClO2 radicals in the photolysis of chlorine in oxygen", J. Am. Chem. Soc. 91, 7712-7727 (1969); DOI: 10.1021/ja50001a036:
σ = (1 - e-1236/T) ∑σv e-1236v/T (v = 0-7) with
σv = (4.35 - 0.55v) × 10-18 cm2 molecule-1
v= vibrational quantum number |
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