The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Halogenated N-compounds(inorg) / INO2 / BroskeZabel(1998)_298K_240,282,342nm(max)

DATAFILE: INO2_BroskeZabel(1998)_298K_240,282,342nm(max).txt
NAME: nitryl iodide
FORMULA: INO2
AUTHOR(YEAR): BroskeZabel(1998)
T: 298K
λ: 240,282,342nm(max)
BIBLIOGRAPHY: R. Bröske and F. Zabel, "Photochemistry and thermochemistry of INO2 and IONO2, presented at the Conference Laboratory experiments of iodine chemistry in the stratosphere - LEXIS", Brussels, 1998, EC Grant Reference: ENV4-CT95-0013 (Ed. A. Cox, G. Poulet, J. Crowley, M.J. Rossi, R.P. Wayne, and F. Zabel)
COMMENTS: Photolysis of I2/NO2/N2 mixtures in the wavelength range 500-700 nm (where NO2 photolysis is impossible for energetic reasons) produced INO2 which was identified by comparison with known IR absorption bands

Absolute cross sections could not be determined because a mass balance was not possible

Taking 1% as an upper limit for the loss of NO2 and assuming the stoichiometric formation of INO2, the data are lower limits for the absorption cross sections of the three maxima

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