The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Halogenated N-compounds(inorg) / NCl3 / ClarkClyne(1969)_300K_210-403nm

DATAFILE: NCl3_ClarkClyne(1969)_300K_210-403nm.txt
NAME: nitrogen trichloride
FORMULA: NCl3
AUTHOR(YEAR): ClarkClyne(1969)
T: 300K
λ: 210-403nm
BIBLIOGRAPHY: T.C. Clark and M.A.A. Clyne, "Kinetic mechanisms in nitrogen-chlorine radical systems: Part 1.-The formation and detection of the NCl2 and N3 free radicals using time-resolved absorption spectrophotometry", Trans. Faraday Soc. 65, 2994-3004 (1969); DOI: 10.1039/TF9696502994
COMMENTS: An absorption spectrophotometric system for the measurement of small optical densities in a low-pressure discharge-flow apparatus was used (deuterium arc as a light source)

Extinction coefficients plotted in Fig. 3a have been digitized and converted to absorption cross sections (conversion factor 3.8235×10-21)

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