The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013


Cross Sections / Halogeno-alkanes+radicals / Chloroalkanes / CCl4 / SPARC(2013)_298K_121.567nm(rec)

DATAFILE: CCl4_SPARC(2013)_298K_121.567nm(rec).txt
NAME: carbon tetrachloride, tetrachloromethane
FORMULA: CCl4
AUTHOR(YEAR): SPARC(2013)
T: 298K
λ: 121.567nm(rec)
BIBLIOGRAPHY: J.B. Burkholder, W. Mellouki, E.L. Fleming, C. George, D.E. Heard, C.H. Jackman, M.J. Kurylo, V.L. Orkin, W.H. Swartz, and T.J. Wallington, "Evaluation of Atmospheric Loss Processes: Photochemistry Supplement", SPARC Lifetimes Report (2013) – SPARC Report No. 6, Chapter 3: Supplement 4, 3S4-1 - 3S4-52 (2013); www.sparc-climate.org/publications/sparc-reports/
COMMENTS: Recommended absorption cross section at the Lyman-α wavelength with an estimated uncertainty factor p(298 K) = 1.2

The value is the average of the interpolated results of

G.C. Causley and B.R. Russell, "The vacuum ultraviolet absorption spectra of the Group IVA tetrachlorides", J. Electron Spectrosc. Relat. Phenom. 11, 383-397 (1977); DOI: 10.1016/0368-2048(77)80015-7,

T. Ibuki, N. Takahashi, A. Hiraya, and K. Shobatake, "CCl21B1) radical formation in VUV photolyses of CCl4 and CBrCl3", J. Chem. Phys. 85, 5717-5722 (1986); DOI: 10.1063/1.451532, and

G.H. Ho, "Absolute photoabsorption cross section of CCl4 in the energy range 6-250 eV", Chem. Phys. 226, 101-111 (1998); 10.1016/S0301-0104(97)00259-0

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