The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Halogeno-alkanes+radicals / Chloroalkanes / CH2Cl / Roussel(1991)_298K_198-215nm

DATAFILE: CH2Cl_Roussel(1991)_298K_198-215nm.txt
NAME: chloromethyl radical
FORMULA: CH2Cl
AUTHOR(YEAR): Roussel(1991)
T: 298K
λ: 198-215nm
BIBLIOGRAPHY: P.B. Roussel, P.D. Lightfoot, F. Caralp, V. Catoire, R. Lesclaux, and W. Forst, "Ultraviolet absorption spectra of the CH2Cl and CHCl2 radicals and the kinetics of their self-recombination reactions from 273 to 686 K", J. Chem. Soc. Faraday Trans. 87, 2367-2377 (1991); DOI: 10.1039/FT9918702367
COMMENTS: Time-resolved UV absorption following the flash photolysis of Cl2/CH3Cl mixtures

Absorption cross sections measured relative to that of CH3O2 at 240 nm with
σ = 4.55×10-18 cm2 molecule-1

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