The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013


Cross Sections / Halogeno-alkanes+radicals / Chloroalkanes / CH3CCl3 / JPL-2015(2015)_298K_170-255nm(rec)

DATAFILE: CH3CCl3_JPL-2015(2015)_298K_170-255nm(rec).txt
NAME: 1,1,1-trichloroethane, methylchloroform
FORMULA: CH3CCl3
AUTHOR(YEAR): JPL-2015(2015)
T: 298K
λ: 170-255nm(rec)
BIBLIOGRAPHY: J. B. Burkholder, S. P. Sander, J. Abbatt, J. R. Barker, R. E. Huie, C. E. Kolb, M. J. Kurylo, V. L. Orkin, D. M. Wilmouth, and P. H. Wine, "Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 18", JPL Publication 15-10, Jet Propulsion Laboratory, Pasadena, 2015 http://jpldataeval.jpl.nasa.gov
COMMENTS: JPL-2015(2015) recommendation:

The earlier recommendations for the absorption cross sections (JPL-2002, JPL-2006, and JPL-2010) habe benn adopted

170-180 nm, mean of the data of

C. Hubrich and F. Stuhl, "Ultraviolet absorption of some halogenated methanes and ethanes of atmospheric interest," J. Photochem. 12, 93-107 (1980); DOI: 10.1016/0047-2670(80)85031-3, and

A.K. Nayak, M.J. Kurylo, and A. Fahr, "UV absorption cross sections of methylchloroform: Temperature-dependent gas and liquid phase measurements," J. Geophys. Res. 100(D6), 11185-11189 (1995); DOI: 10.1029/95JD00695,

185-205 nm, mean of the data of

N. Vanlaethem-Meurée, J. Wisemberg, and P.C. Simon, "Ultraviolet absorption spectrum of methylchloroform in the vapor phase," Geophys. Res. Lett. 6, 451-454 (1979); DOI: 10.1029/GL006i006p00451 ,

C. Hubrich and F. Stuhl, "Ultraviolet absorption of some halogenated methanes and ethanes of atmospheric interest," J. Photochem. 12, 93-107 (1980); DOI: 10.1016/0047-2670(80)85031-3, and

A.K. Nayak, M.J. Kurylo, and A. Fahr, "UV absorption cross sections of methylchloroform: Temperature-dependent gas and liquid phase measurements," J. Geophys. Res. 100(D6), 11185-11189 (1995); DOI: 10.1029/95JD00695,

210-240 nm, mean of the data

N. Vanlaethem-Meurée, J. Wisemberg, and P.C. Simon, "Ultraviolet absorption spectrum of methylchloroform in the vapor phase," Geophys. Res. Lett. 6, 451-454 (1979); DOI: 10.1029/GL006i006p00451, and

A.K. Nayak, M.J. Kurylo, and A. Fahr, "UV absorption cross sections of methylchloroform: Temperature-dependent gas and liquid phase measurements," J. Geophys. Res. 100(D6), 11185-11189 (1995); DOI: 10.1029/95JD00695,

245-255 nm, extrapolation of the 210-240-nm data, log σ(λ) = -1.59792 - 0.08066 λ

The parameterization of the cross section temperature dependence (210-300 K, 182-240 nm) using an empirical polynomial expansion

log10 σ(λ, T) = ∑An λn + (T–273) × ∑Bnλn

with the following parameters An and Bn reported by

D. Gillotay and P. C. Simon, "Ultraviolet absorption cross-sections of photoactive species of stratospheric interest. Part 1 : The Halocarbons", Aeronomica Acta A, 356, 1-173 (1990):

A0 = 341.085191         B0 = –1.660090
A1 = –7.273362        B1 = 3.079969 × 10–2
A2 = 5.498387 × 10–2       B2 = –2.106719 × 10–4
A3 = –1.827552 × 10–4        B3 = 6.264984 × 10–7
A4 = 2.238640 × 10–7       B4 = –6.781342 × 10–10

is recommended

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