JPL-2015(2015) recommendation:
The earlier recommendations for the absorption cross sections (JPL-2002, JPL-2006, and JPL-2010) habe benn adopted
170-180 nm, mean of the data of
C. Hubrich and F. Stuhl, "Ultraviolet absorption of some halogenated methanes and ethanes of atmospheric interest," J. Photochem. 12, 93-107 (1980); DOI: 10.1016/0047-2670(80)85031-3, and
A.K. Nayak, M.J. Kurylo, and A. Fahr, "UV absorption cross sections of methylchloroform: Temperature-dependent gas and liquid phase measurements," J. Geophys. Res. 100(D6), 11185-11189 (1995); DOI: 10.1029/95JD00695,
185-205 nm, mean of the data of
N. Vanlaethem-Meurée, J. Wisemberg, and P.C. Simon, "Ultraviolet absorption spectrum of methylchloroform in the vapor phase," Geophys. Res. Lett. 6, 451-454 (1979); DOI: 10.1029/GL006i006p00451 ,
C. Hubrich and F. Stuhl, "Ultraviolet absorption of some halogenated methanes and ethanes of atmospheric interest," J. Photochem. 12, 93-107 (1980); DOI: 10.1016/0047-2670(80)85031-3, and
A.K. Nayak, M.J. Kurylo, and A. Fahr, "UV absorption cross sections of methylchloroform: Temperature-dependent gas and liquid phase measurements," J. Geophys. Res. 100(D6), 11185-11189 (1995); DOI: 10.1029/95JD00695,
210-240 nm, mean of the data
N. Vanlaethem-Meurée, J. Wisemberg, and P.C. Simon, "Ultraviolet absorption spectrum of methylchloroform in the vapor phase," Geophys. Res. Lett. 6, 451-454 (1979); DOI: 10.1029/GL006i006p00451, and
A.K. Nayak, M.J. Kurylo, and A. Fahr, "UV absorption cross sections of methylchloroform: Temperature-dependent gas and liquid phase measurements," J. Geophys. Res. 100(D6), 11185-11189 (1995); DOI: 10.1029/95JD00695,
245-255 nm, extrapolation of the 210-240-nm data, log σ(λ) = -1.59792 - 0.08066 λ
The parameterization of the cross section temperature dependence (210-300 K, 182-240 nm) using an empirical polynomial expansion
log10 σ(λ, T) = ∑An λn + (T–273) × ∑Bnλn
with the following parameters An and Bn reported by
D. Gillotay and P. C. Simon, "Ultraviolet absorption cross-sections of photoactive species of stratospheric interest. Part 1 : The Halocarbons", Aeronomica Acta A, 356, 1-173 (1990):
A0 = 341.085191 B0 = –1.660090
A1 = –7.273362 B1 = 3.079969 × 10–2
A2 = 5.498387 × 10–2 B2 = –2.106719 × 10–4
A3 = –1.827552 × 10–4 B3 = 6.264984 × 10–7
A4 = 2.238640 × 10–7 B4 = –6.781342 × 10–10
is recommended |