| COMMENTS: | Recommended absorption cross section at the Lyman-α wavelength with an estimated uncertainty factor p(298 K) = 1.15 The value is based on the results (which are are in reasonable agreement at 121.567 nm to within 30%) of
B.R Russell, L.O. Edwards, and J.W. Raymonda, "Vacuum ultraviolet absorption spectra of the chloromethanes", J. Am. Chem. Soc. 95, 2129-2133 (1973); DOI: ,
J.W. Raymonda, L.O. Edwards, and B.R. Russell, "Vacuum ultraviolet absorption spectra of some chloroalkanes", J. Am. Chem. Soc. 96, 1708-1712 (1974); DOI: 10.1021/ja00813a011,
D.T. Truch, D.R. Salomon, and D.A. Armstrong, "Rydberg spectroscopy of methyl chloride", J. Mol. Spectrosc. 78, 31-39 (1979); DOI: 10.1016/0022-2852(79)90033-X,
L.C. Lee and M. Suto, "Fluorescence yields from photodissociative excitation of chloromethanes by vacuum ultraviolet radiation", Chem. Phys. 114, 423-429 (1987); DOI: 10.1016/0301-0104(87)85056-5,
T.N. Olney, G. Cooper, W.F. Chan, G.R. Burton, C.E. Brion, and K.H. Tan, "Absolute photoabsorption (6-350 eV) and photoionization (11-80 eV) of methyl chloride using dipole electron scattering and synchrotron radiation spectroscopies", Chem. Phys. 205, 421-439 (1996); DOI: 10.1016/0301-0104(95)00429-7,
R.A. Brownsword, M. Hillenkamp, T. Laurent, R.K. Vatsa, H.-R. Volpp, and J. Wolfrum, "Photodissociation dynamics of the chloromethanes at the Lyman-%alpha; wavelength (121.6 nm)", J. Chem. Phys. 106, 1359-1366 (1997); DOI: 10.1063/1.473304,
R. Locht, B. Leyh, A. Hoxha, H.W. Jochims, and H. Baumgärtel, "The vacuum UV absorption spectrum of methyl chloride (CH3Cl) and its perdeuterated isotopomer CD3Cl. I. A Rydberg series analysis", Chem. Phys. 272, 259-275 (2001); DOI: 10.1016/S0301-0104(01)00464-5,
R.K. Vatsa and H.-R. Volpp, "Absorption cross sections for some atmospherically important molecules at the H atom Lyman-%alpha; wavelength (121.567 nm)", Chem. Phys. Lett. 340, 289-295 (2001); DOI: 10.1016/S0009-2614(01)00373-6, and
S. Eden, P. Limão-Vieira, S.V. Hoffmann, and N.J. Mason, "VUV absorption in CF3X (X = Cl, Br, I) fluoroalkanes", Chem. Phys. 323, 313-333 (2006); DOI: 10.1016/j.chemphys.2005.09.040 |
