The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013


Cross Sections / Halogeno-alkanes+radicals / Freons-CFC(C,F,Cl) / CCl2FCCl2F(CFC-112) / Davis(2016)_230K_192.5-215nm

DATAFILE: CCl2FCCl2F(CFC-112)_Davis(2016)_230K_192.5-215nm.txt
NAME: 1,1,2,2-tetrachloro-1,2-difluoroethane (CFC-112)
FORMULA: CCl2FCCl2F(CFC-112)
AUTHOR(YEAR): Davis(2016)
T: 230K
λ: 192.5-215nm
BIBLIOGRAPHY: M.E. Davis, F. Bernard, M.R. McGillen, E.L. Fleming, and J.B. Burkholder, "UV and infrared absorption spectra, atmospheric lifetimes, and ozone depletion and global warming potentials for CCl2FCCl2F (CFC-112), CCl3CClF2 (CFC-112a), CCl3CClF2 (CFC-113a), and CCl2FCF3 (CFC-114a)", Atmos. Chem. Phys. 16, 8043–8052 (2016); DOI: 10.5194/acp-16-8043-2016
COMMENTS: The output of a stable 30W deuterium (D2) lamp light source was collimated and directed through a jacketed 90.4-0.3 cm single-pass absorption cell, and the beam exiting the cell was focused onto the entrance slit (150 μm) of a 0.25m monochromator (∼1 nm resolution) and detected using a photomultiplier tube (PMT)

Parameterization of the temperature dependence valid over the wavelength range 192.5 to 235 nm for temperatures between 230 and 323 K

ln (σ(λ,T)) = ∑i Ai λii + (T - 296) ∑i Bi λii

with the following parameters Ai and Bi:

-----------------------------------------------------------------
i    Ai         Bi
-----------------------------------------------------------------

0    -1488.6207      6.04688
1   18.43604      -0.0801501
2   -0.02897393     0.0001201698
3   -0.00051504703    2.6103669×10-6
4    2.644261×10-6    -1.3959106×10-8
5   -3.7258313×10-9    2.0719264×10-11

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