The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Halogeno-alkanes+radicals / Freons-CFC(C,F,Cl) / CF2ClCF2Cl(CFC-114) / Robbins(1976)_295K_174-214nm

DATAFILE: CF2ClCF2Cl(CFC-114)_Robbins(1976)_295K_174-214nm.txt
NAME: 1,1,2,2-tetrafluoro-1,2-dichloroethane (CFC-114)
FORMULA: CF2ClCF2Cl(CFC-114)
AUTHOR(YEAR): Robbins(1976)
T: 295K
λ: 174-214nm
BIBLIOGRAPHY: D.E. Robbins, "UV photoabsorption cross section for halocarbons", Int. Conf. Stratosphere and Related Problems, Logan (USA), 1976
COMMENTS: The report of D. E. Robbins has been published in JPL Publication 77-12, pp. 255-257

The cross section measurements (at 2 nm intervals) were carried out utilizing a monochromator to provide UV radiation with a 0.07 nm bandwidth and, as a source of UV radiation, a lamp which produced a discharge in H2 gas

The data are to be found also in the reviews of

D. Gillotay and P.C. Simon, "Ultraviolet absorption cross-sections of photoactive species of stratospheric interest. Part 1 : The Halocarbons.," Aeronomica Acta A 356, 1-173 (1990), and

R.T. Watson, "Rate constants for reactions of ClOx of atmospheric interest," J. Phys. Chem. Ref. Data 6, 871-917 (1977)

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