The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013


Cross Sections / Halogeno-alkanes+radicals / Halons(C,H,F,Cl,Br) / CF2BrCF2Br(Halon-2402) / JPL-2015(2015)_296K_170-350nm(rec)

DATAFILE: CF2BrCF2Br(Halon-2402)_JPL-2015(2015)_296K_170-350nm(rec).txt
NAME: 1,1,2,2-tetrafluoro-1,2-dibromoethane (Halon-2402)
FORMULA: CF2BrCF2Br(Halon-2402)
AUTHOR(YEAR): JPL-2015(2015)
T: 296K
λ: 170-350nm(rec)
BIBLIOGRAPHY: J. B. Burkholder, S. P. Sander, J. Abbatt, J. R. Barker, R. E. Huie, C. E. Kolb, M. J. Kurylo, V. L. Orkin, D. M. Wilmouth, and P. H. Wine, "Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 18", JPL Publication 15-10, Jet Propulsion Laboratory, Pasadena, 2015 http://jpldataeval.jpl.nasa.gov
COMMENTS: JPL-2015 recommendation:

170-264 nm, JPL-2002, JPL-2006, and JPL-2010 recommendations adopted

170-186 nm, data of

D. Gillotay, P.C. Simon, and L. Dierckx, "Temperature dependence of ultraviolet absorption cross-sections of brominated methanes and ethanes," Aeronomica Acta A 335, 1-25 (1988),

188-194 nm,

values estimated by smoothing the absorption curve,

196-264 nm, mean of the values of

L.T. Molina, M.J. Molina, and F.S. Rowland, "Ultraviolet absorption cross sections of several brominated methanes and ethanes of atmospheric interest," J. Phys. Chem. 86, 2672-2676 (1982); DOI: 10.1021/j100211a023,

D. Gillotay, P.C. Simon, and L. Dierckx, "Temperature dependence of ultraviolet absorption cross-sections of brominated methanes and ethanes," Aeronomica Acta A 335, 1-25 (1988),

J.B. Burkholder, R.R. Wilson, T. Gierczak, R. Talukdar, S.A. McKeen, J.J. Orlando, G.L. Vaghjiani, and A.R. Ravishankara, "Atmospheric fate of CF3Br, CF2Br2, CF2ClBr, and CF2BrCF2Br," J. Geophys. Res. 96(D3), 5025-5043 (1991); DOI: 10.1029/90JD02735, and

L. Orkin and E.E. Kasimovskaya, "Ultraviolet absorption spectra of some Br-containing haloalkanes," J. Atmos. Chem. 21, 1-11 (1995); DOI: 10.1007/BF00712435,

266-350 nm, parameterization of

D.K. Papanastasiou, N. Rontu Carlon, A. Neuman, E.L. Fleming, C.H. Jackman, and J.B. Burkholder, "Revised UV absorption spectra, ozone depletion potentials, and global warming potentials for the ozone-depleting substances CF2Br2, CF2ClBr, and CF2BrCF2Br", Geophys. Res. Lett. 40, 464-469 (2013); DOI: 10.1002/grl.50121,

with values at λ ≥ 322 nm obtained by an extrapolation

The recommended parameterization of the cross section temperature dependence: for wavelengths > 264 nm is taken from Papanastasiou et al.:

ln (σ(λ,T)) = ∑i Ai (λ-λ*)i × [1 + (296 – T) ∑i Bi (λ-λ*)i]

with the following parameters Ai and Bi and λ* = 274.64 nm:

-----------------------------------------------------
i    Ai        Bi
-----------------------------------------------------

0  -48.3611     0.0001877
1  -0.1595      7.252×10-6
2  -1.026×10-4     2.917×10-7
3  -1.334×10-5   -1.725×10-9
4   1.458×10-7      -2.675×10-11

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