The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013


Cross Sections / Halogeno-alkanes+radicals / Halons(C,H,F,Cl,Br) / CF3Br(Halon-1301) / Bernard(2015)_250K_195-235nm

DATAFILE: CF3Br(Halon-1301)_Bernard(2015)_250K_195-235nm.txt
NAME: trifluorobromomethane (Halon-1301)
FORMULA: CF3Br(Halon-1301)
AUTHOR(YEAR): Bernard(2015)
T: 250K
λ: 195-235nm
BIBLIOGRAPHY: F. Bernard, M.R. McGillen, E.L. Fleming, C.H. Jackman, and J.B. Burkholder, "CBrF3 (Halon-1301): UV absorption spectrum between 210 and 320 K, atmospheric lifetime, and ozone depletion potential", J. Photochem. Photobiol. A: Chem. 306, 13-20 (2015); DOI: 10.1016/j.jphotochem.2015.03.012
COMMENTS: Absorption cross sections were determined at nine discrete wavelengths between 195 and 235 nm (5 nm intervals) and at six temperatures between 210 and 320 K

The experimental apparatus consisted of a 30 W D2 lamp, a jacketed single pass absorption cell with a 90.4 cm pathlength, a 0.25 m monochromator with a photomultiplier tube detector

Parameterization of the temperature dependence valid over the 190−235 nm wavelength range and 210−320 K temperature range:

ln(σ(λ, T)) = Σ Ai λi + (T - 296) × Σ Bi λi (i = 0 - 4)

with the following parameters Ai and Bi:

------------------------------------------------
i    Ai        Bi
------------------------------------------------

0  315.204     0.00077
1  -8.03836     -5.6975×10-4
2  0.006362234    1.1304×10-5
3    -2.1356×10-4   −7.3977×10-8
4  2.5779×10-7       1.52790×10-10

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