The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013


Cross Sections / Halogeno-alkanes+radicals / Halons(C,H,F,Cl,Br) / CF3Br(Halon-1301) / GillotaySimon(1989)_230K_168-280nm(2nm)

DATAFILE: CF3Br(Halon-1301)_GillotaySimon(1989)_230K_168-280nm(2nm).txt
NAME: trifluorobromomethane (Halon-1301)
FORMULA: CF3Br(Halon-1301)
AUTHOR(YEAR): GillotaySimon(1989)
T: 230K
λ: 168-280nm(2nm)
BIBLIOGRAPHY: D. Gillotay and P.C. Simon, "Ultraviolet absorption spectrum of trifluoro-bromo-methane, difluoro-dibromo-methane and difluoro-bromo-chloro-methane in the vapor phase", Aeronomica Acta A 343, 1-40 (1989); J. Atmos. Chem. 8, 41-62 (1989); DOI: 10.1007/BF00053815
COMMENTS: Absorption measurements at 210 to 295 K using a single-beam equipment with a maximum resolution of 0.015 nm

Selected values at 2-nm intervals

Data also in

D. Gillotay, P.C. Simon, and L. Dierickx, Temperature dependence of ultraviolet absorption cross-sections of brominated methanes and ethanes, in Quadrennial Ozone Symposium, Göttingen, RFA, 1988; Aeronomica Acta A, 335, 1-25 (1988),

and in the review article of

D. Gillotay and P.C. Simon, "Ultraviolet absorption cross-sections of photoactive species of stratospheric interest. Part 1: The Halocarbons", Aeronomica Acta A 356, 1-173 (1990)

Parameterization of the temperature dependence valid over the wavelength range 178 to 280 nm and for temperatures between 220 and 300 K

log10 σ(λ,T) = ∑An λn + (T-273) × ∑ Bn λn, n = 0-4,

with the following parameters An and Bn:

------------------------------------------------------------
n   An        Bn
------------------------------------------------------------
0  62.563       -9.1755×10-1
1  -2.0068      1.8575×10-2
2  1.6592×10-2     -1.3857×10-4
3  -5.6465×10-5    4.5066×10-7
4  6.7459×10-10    5.3803×10-10

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