When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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DATAFILE: | CH2BrI_IUPAC(2008)_298K_215-390nm(rec).txt |
NAME: | bromoiodomethane |
FORMULA: | CH2BrI |
AUTHOR(YEAR): | IUPAC(2008) |
T: | 298K |
λ: | 215-390nm(rec) |
BIBLIOGRAPHY: |
R. Atkinson, D.L. Baulch, R.A. Cox, J.N. Crowley, R.F. Hampson, R.G. Hynes, M.E. Jenkin, M.J. Rossi, J. Troe, and T.J. Wallington, "Evaluated kinetic and photochemical data for atmospheric chemistry: Volume IV - gas phase reactions of organic halogen species",
Atmos. Chem. Phys. 8, 4141-4496 (2008);
DOI: 10.5194/acp-8-4141-2008
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COMMENTS: | IUPAC(2008) recommendation: Data of J.C. Mössinger, D.E. Shallcross, and R.A. Cox, "UV-VIS absorption cross-sections and atmospheric lifetimes of CH2Br2, CH2I2, and CH2BrI," J. Chem. Soc. Faraday Trans. 94, 1391-1396 (1998); DOI: 10.1039/A709160E The temperature dependence ln σ(T) = ln σ(298K) + B × (T - 298) and the temperature coefficients B (273-348 K): -------------------
λ 103 B
(nm) (K-1)
-------------------
215 -2.16
220 -0.12
225 1.34
230 2.06
235 2.05
240 1.01
245 0.00
250 -0.58
255 -1.16
260 -1.29
265 -1.45
270 -1.73
275 -1.22
280 -0.94
285 -0.53
290 0.10
295 0.63
300 1.03
305 1.13
310 1.41
315 1.52
320 1.71
325 2.36
330 2.99
335 3.89
340 4.79
345 5.74
350 6.73
355 9.47
360 11.50
365 11.60
370 14.30
375 17.40
are also adopted from the work of Mössinger et al. (1998) |
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