When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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| DATAFILE: | CH2BrI_JPL-2010(2011)_298K_215-390nm(rec).txt |
| NAME: | bromoiodomethane |
| FORMULA: | CH2BrI |
| AUTHOR(YEAR): | JPL-2010(2011) |
| T: | 298K |
| λ: | 215-390nm(rec) |
| BIBLIOGRAPHY: |
S.P. Sander, J. Abbatt, J. R. Barker, J. B. Burkholder, R. R. Friedl, D. M. Golden, R. E. Huie, C. E. Kolb, M. J. Kurylo, G. K. Moortgat, V. L. Orkin and P. H. Wine, "Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 17",
JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, 2011; http://jpldataeval.jpl.nasa.gov/
|
| COMMENTS: | JPL-2010 recommendation, adopting the earlier recommendations of
S.P. Sander, R.R. Friedl, D.M. Golden, M.J. Kurylo, R.E. Huie, V.L. Orkin, G.K. Moortgat, A.R. Ravishankara, C.E. Kolb, M.J. Molina, and B.J. Finlayson-Pitts, “Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies. Evaluation Number 14“, JPL Publication 02-25, Jet Propulsion Laboratory, Pasadena, 2002; http://jpldataeval.jpl.nasa.gov/, and
S.P. Sander, R.R. Friedl, D.M. Golden, M.J. Kurylo, G.K. Moortgat, H. Keller-Rudek, P.H. Wine, A.R. Ravishankara, C.E. Kolb, M.J. Molina, B.J. Finlayson-Pitts, R.E. Huie, V.L. Orkin, “Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies. Evaluation Number 15“, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, 2006; http://jpldataeval.jpl.nasa.gov/:
215-390 nm, absorption cross sections of J.C. Mössinger, D.E. Shallcross, and R.A. Cox, "UV-VIS absorption cross-sections and atmospheric lifetimes of CH2Br2, CH2I2, and CH2BrI," J. Chem. Soc. Faraday Trans. 94, 1391-1396 (1998); DOI: 10.1039/A709160E Temperature coefficients B: 273-348 K, J.C. Mössinger, D.E. Shallcross, and R.A. Cox, "UV-VIS absorption cross-sections and atmospheric lifetimes of CH2Br2, CH2I2, and CH2BrI," J. Chem. Soc. Faraday Trans. 94, 1391-1396 (1998); DOI: 10.1039/A709160E, ln σ(λ, T) = ln σ(λ, 298 K) + B × (T - 298) with -------------------
λ 103 B
(nm) (K-1)
-------------------
215 -2.16
220 -0.12
225 1.34
230 2.06
235 2.05
240 1.01
245 0.00
250 -0.58
255 -1.16
260 -1.29
265 -1.45
270 -1.73
275 -1.22
280 -0.94*)
285 -0.53
290 0.10
295 0.63
300 1.03
305 1.13
310 1.41
315 1.52
320 1.71
325 2.36
330 2.99
335 3.89
340 4.79
345 5.74
350 6.73
355 9.47
360 11.50
365 11.60
370 14.30
375 17.40
*) B(280 nm) erroneously +0.00094 in Table 1; corrected to -0.00094, after personal communication with J. Mössinger (March 2001) |
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