When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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DATAFILE: | CH2BrI_Mossinger(1998)_273K_215-375nm(calc).txt |
NAME: | bromoiodomethane |
FORMULA: | CH2BrI |
AUTHOR(YEAR): | Mossinger(1998) |
T: | 273K |
λ: | 215-375nm(calc) |
BIBLIOGRAPHY: |
J.C. Mössinger, D.E. Shallcross, and R.A. Cox, "UV-VIS absorption cross-sections and atmospheric lifetimes of CH2Br2, CH2I2, and CH2BrI",
J. Chem. Soc. Faraday Trans. 94, 1391-1396 (1998);
DOI: 10.1039/A709160E
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COMMENTS: | Absorption measurements at 273 to 348 K using a dual-beam diode array spectrometer (spectral resolution ∼0.6 nm) Calculated absorption cross sections using the values measured at 298 K, the equation ln σ(λ, T) = ln σ(λ, 298 K) + B × (T - 298), and the temperature coefficients B: -------------------
λ 103 B
(nm) (K-1)
-------------------
215 -2.16
220 -0.12
225 1.34
230 2.06
235 2.05
240 1.01
245 0.00
250 -0.58
255 -1.16
260 -1.29
265 -1.45
270 -1.73
275 -1.22
280 -0.94*)
285 -0.53
290 0.10
295 0.63
300 1.03
305 1.13
310 1.41
315 1.52
320 1.71
325 2.36
330 2.99
335 3.89
340 4.79
345 5.74
350 6.73
355 9.47
360 11.50
365 11.60
370 14.30
375 17.40 *) B(280 nm) erroneously +0.00094 in Table 1; corrected to -0.00094, after personal communication with Juliane Mössinger (March 2001) |
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