S.P. Sander, R.R. Friedl, D.M. Golden, M.J. Kurylo, R.E. Huie, V.L. Orkin, G.K. Moortgat, A.R. Ravishankara, C.E. Kolb, M.J. Molina, and B.J. Finlayson-Pitts, “Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies. Evaluation Number 14“, JPL Publication 02-25, Jet Propulsion Laboratory, Pasadena, 2002; http://jpldataeval.jpl.nasa.gov/ , and

S.P. Sander, R.R. Friedl, D.M. Golden, M.J. Kurylo, G.K. Moortgat, H. Keller-Rudek, P.H. Wine, A.R. Ravishankara, C.E. Kolb, M.J. Molina, B.J. Finlayson-Pitts, R.E. Huie, V.L. Orkin, “Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies. Evaluation Number 15“, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, 2006; http://jpldataeval.jpl.nasa.gov/ :

Absorption cross sections σ:

210-230 nm, mean of the data of

M.E. Jenkin, T.P. Murrells, S.J. Shalliker, and G.D, Hayman, "Kinetics and product study of the self-reactions of allyl and allyl peroxy radicals," J. Chem. Soc. Faraday Trans. 89, 433-446 (1993); DOI: 10.1039/FT9938900433,

A. Fahr, A.K. Nayak, and M.J. Kurylo, "The ultraviolet absorption cross sections of CH₃I temperature dependent gas and liquid phase measurements," Chem. Phys. 197, 195-203 (1995); DOI: 10.1016/0301-0104(95)00172-K , and

C.M. Roehl, J.B. Burkholder, G.K. Moortgat, A.R. Ravishankara, and P.J. Crutzen, "Temperature dependence of UV absorption cross sections and atmospheric implications of several alkyl iodides," J. Geophys. Res. 102(D11), 12819-12829 (1997); DOI: 10.1029/97JD00530 ,

235-330 nm, mean of the data of

M.E. Jenkin, T.P. Murrells, S.J. Shalliker, and G.D, Hayman, "Kinetics and product study of the self-reactions of allyl and allyl peroxy radicals," J. Chem. Soc. Faraday Trans. 89, 433-446 (1993); DOI: 10.1039/FT9938900433,

A. Fahr, A.K. Nayak, and M.J. Kurylo, "The ultraviolet absorption cross sections of CH₃I temperature dependent gas and liquid phase measurements," Chem. Phys. 197, 195-203 (1995); DOI: 10.1016/0301-0104(95)00172-K ,

O.V. Rattigan, D.E. Shallcross, and R.A. Cox, "UV absorption cross-sections and atmospheric photolysis rates of CF₃I, CH₃I, C₂H₅I and CH₂ICl," J. Chem. Soc. Faraday Trans. 93, 2839-2846 (1997); DOI: 10.1039/A701529A, and

C.M. Roehl, J.B. Burkholder, G.K. Moortgat, A.R. Ravishankara, and P.J. Crutzen, "Temperature dependence of UV absorption cross sections and atmospheric implications of several alkyl iodides," J. Geophys. Res. 102, 12819-12829 (1997; DOI: 10.1029/97JD00530),

335-350 nm, mean of the data of

A. Fahr, A.K. Nayak, and M.J. Kurylo, "The ultraviolet absorption cross sections of CH₃I temperature dependent gas and liquid phase measurements," Chem. Phys. 197, 195-203 (1995); DOI: 10.1016/0301-0104(95)00172-K ,

O.V. Rattigan, D.E. Shallcross, and R.A. Cox, "UV absorption cross-sections and atmospheric photolysis rates of CF₃I, CH₃I, C₂H₅I and CH₂ICl," J. Chem. Soc. Faraday Trans. 93, 2839-2846 (1997); DOI: 10.1039/A701529A, and

C.M. Roehl, J.B. Burkholder, G.K. Moortgat, A.R. Ravishankara, and P.J. Crutzen, "Temperature dependence of UV absorption cross sections and atmospheric implications of several alkyl iodides," J. Geophys. Res. 102(D11), 12819-12829 (1997); DOI: 10.1029/97JD00530 ,

355-365 nm, data of

O.V. Rattigan, D.E. Shallcross, and R.A. Cox, "UV absorption cross-sections and atmospheric photolysis rates of CF₃I, CH₃I, C₂H₅I and CH₂ICl," J. Chem. Soc. Faraday Trans. 93, 2839-2846 (1997); DOI: 10.1039/A701529A.

Temperature coefficients a₁ and a₂:

210-298 K,

C.M. Roehl, J.B. Burkholder, G.K. Moortgat, A.R. Ravishankara, and P.J. Crutzen, "Temperature dependence of UV absorption cross sections and atmospheric implications of several alkyl iodides," J. Geophys. Res. 102(D11), 12819-12829 (1997); DOI: 10.1029/97JD00530 ,

σ(λ, T) = σ(298 K) [1 + a₁(T - 298) + a₂(T - 298)²] with

--------------------------------
λ    10³ a₁ 10⁵ a₂
(nm)  (K^-1)   (K^-2)
--------------------------------
200  6.25   2.62
205  8.43   4.87
210  3.07   2.42
215  2.61   2.28
220  1.06   1.22
225  1.74   1.96
230  1.47   1.67
235  1.91   2.04
240  1.74   2.06
245  1.52   2.15
250  1.20   2.11
255  0.890  1.95
260  0.882  1.93
265  1.21   2.00
270  1.77   2.11
275  2.52   2.12
280  3.62   2.24
285  4.84   2.38
290  6.14   2.57
295  7.27   2.91
300  7.82   3.53
305  7.82   3.85
310  7.37   3.71
315  6.98   3.47
320  7.39   3.54
325  7.23   2.82
330  8.93   3.74
335 10.88  4.88
340 11.30  4.46
345 15.68  8.44
350 15.94  8.22

Temperature coefficients B:

243-333 K,

O.V. Rattigan, D.E. Shallcross, and R.A. Cox, "UV absorption cross-sections and atmospheric photolysis rates of CF₃I, CH₃I, C₂H₅I and CH₂ICl," J. Chem. Soc. Faraday Trans. 93, 2839-2846 (1997); DOI: 10.1039/A701529A,

ln σ(λ, T) = ln σ(λ, 298 K) + B × (T - 298) with

--------------------
λ   10³ B
(nm) (K^-1)
--------------------
235  0.67
240  0.61
245  0.34
250  0.08
255 -0.10
260 -0.12
265  0.10
270  0.54
275  1.33
280  2.43
285  3.74
290  4.98
295  6.38
300  6.97
305  6.84
310  6.78
315  6.75
320  6.53
325  6.79
330  7.82
335  9.34
340 10.95
345 13.58
350 16.83
355 18.91
360 17.28
365 23.63