When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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DATAFILE: | CH2=CClCH2_AtkinsonHudgens(2000)_298K_240nm.txt |
NAME: | 2-chloroallyl radical |
FORMULA: | CH2=CClCH2 |
AUTHOR(YEAR): | AtkinsonHudgens(2000) |
T: | 298K |
λ: | 240nm |
BIBLIOGRAPHY: |
D.B. Atkinson and J.W. Hudgens, "Chlorination chemistry. 2. Rate coefficients, reaction mechanism, and spectrum of the chlorine adduct with allene",
J. Phys. Chem. A 104, 811-818 (2000);
DOI: 10.1021/jp9927247
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COMMENTS: |
Laser photolysis of allene-chlorine mixtures and cavity ring-down detection of the CH2=CClCH2 radical The absorption spectrum, absorbance vs. wavelength, at 238-252 nm is shown in Fig. 1 The absolute absorption cross section at 240 nm was measured relative to the absorption cross section of the C2H5O2 radical.
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