The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Halogeno-alkenes+radicals / Fluoroalkenes / (E)-CF3CH=CHCF3 / Baasandorj(2018)_296K_184.9nm

DATAFILE: (E)-CF3CH=CHCF3_Baasandorj(2018)_296K_184.9nm.txt
NAME: (E)-1,1,1,4,4,4-hexafluoro-2-butene, HFO-1336mzz(E)
FORMULA: (E)-CF3CH=CHCF3
AUTHOR(YEAR): Baasandorj(2018)
T: 296K
λ: 184.9nm
BIBLIOGRAPHY: M. Baasandorj, P. Marshall, R.L. Waterland, A.R. Ravishankara, and J.S. Burkholder,, "Rate coefficient measurements and theoretical analysis of the OH +(E)-CF3CH=CHCF3 reaction", J. Phys. Chem. A 122, 4635-4646 (2018) DOI: 10.1021/acs.jpca.8b02771
COMMENTS: Absorption measurements using a Hg pen-ray lamp light source, a 100 cm long absorption cell, and a 185 nm band-pass filter mounted in front of a solar-blind photodiode detector

A least-squares analysis of the absorbance A vs. (E)-CF3CH=CHCF3 concentrations ((7.35 - 27.5)×1016 molecules cm-3) yielded σ(184.9 nm)

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