When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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| DATAFILE: | CH3OCl_IUPAC(2008)_295K_200-460nm(rec).txt |
| NAME: | methyl hypochlorite |
| FORMULA: | CH3OCl |
| AUTHOR(YEAR): | IUPAC(2008) |
| T: | 295K |
| λ: | 200-460nm(rec) |
| BIBLIOGRAPHY: |
R. Atkinson, D.L. Baulch, R.A. Cox, J.N. Crowley, R.F. Hampson, R.G. Hynes, M.E. Jenkin, M.J. Rossi, J. Troe, and T.J. Wallington, "Evaluated kinetic and photochemical data for atmospheric chemistry: Volume IV - gas phase reactions of organic halogen species",
Atmos. Chem. Phys. 8, 4141-4496 (2008);
DOI: 10.5194/acp-8-4141-2008
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| COMMENTS: | IUPAC(2008) recommendation: There is very good agreement between the cross sections presented in the studies of J.N. Crowley, F. Helleis, R. Müller, G.K. Moortgat, P.J. Crutzen, and J.J. Orlando, "CH3OCl: UV/visible absorption cross sections, J values and atmospheric significance," J. Geophys. Res. 99(D10), 20683-20688 (1994); DOI: 10.1029/94JD01829, and T.P.W. Jungkamp, U. Kirchner, M. Schmidt, and R.N. Schindler, "UV-absorption cross section data for the hypochlorites ROCl (R = H, CH3, C2H5, i-C3H7, t-C4H9)," J. Photochem. Photobiol. 91, 1-6 (1995); DOI: 10.1016/1010-6030(95)04074-P, for λ ≥ 260 nm, though some differences are observed at the short wavelength end of the spectra.
The data of Crowley et al., which cover a larger wavelength range and extent further into the actinic region, are preferred |
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