When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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DATAFILE: | HO2NO2_Knight(2002)_273K_280-350nm.txt |
NAME: | peroxynitric acid |
FORMULA: | HO2NO2 |
AUTHOR(YEAR): | Knight(2002) |
T: | 273K |
λ: | 280-350nm |
BIBLIOGRAPHY: |
G. Knight, A.R. Ravishankara, and J.B. Burkholder, "UV absorption cross sections of HO2NO2 between 343 and 273 K",
Phys. Chem. Chem. Phys. 4, 1432-1437 (2002);
DOI: 10.1039/B108904H
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COMMENTS: | Absorption measurements at 273, 296, 318, and 343 K and over the wavelength range 220-350 nm using a 0.5 m spectrometer with a 1024 element diode array detector and a 30 W D2 lamp light source; spectral resolution ∼1.5 nm
The temperature dependence has been parameterized by a simple two component absorption model:
σ(T, λ) = σ0(λ)/Q + σ1(λ)(1 - 1/Q), where Q = 1 + exp(-ΔE/(0.69T)) and ΔE = 988 cm-1.
The spectra have been scaled to the reported cross section data at 250-270 nm of
L.T. Molina and M.J. Molina, "UV absorption cross sections of HO2NO2 acid vapor," J. Photochem. 15, 97-108 (1981), and R.J. Singer, J.N. Crowley, J.P. Burrows, W. Schneider, and G.K. Moortgat, "Measurement of the absorption cross-section of peroxynitric acid between 210 and 330 nm in the range 253 -298 K," J. Photochem. Photobiol. 48, 17-32 (1989) |
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