When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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DATAFILE: | (CH3)2COO_Liu(2014)_298K_288-368nm.txt |
NAME: | acetone oxide |
FORMULA: | (CH3)2COO |
AUTHOR(YEAR): | Liu(2014) |
T: | 298K |
λ: | 288-368nm |
BIBLIOGRAPHY: |
F. Liu, J.M. Beames, A.M. Green, and M.I. Lester, "UV spectroscopic characterization of dimethyl- and ethyl-substituted carbonyl oxides",
J. Phys. Chem. A 118, 2298-2306 (2014);
DOI: 10.1021/jp412726z
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COMMENTS: | Synthesis of the Criegee intermediate by photolysis (118 nm) of a (CH3)2CI2 (2,2-diiodopropane) - O2 - Ar gas mixture and subsequent supersonic expansion;
absorption measurements of the isolated (CH3(2COO species by electronic excitation
of the B ← X transition using tunable UV laser radiation in the wavelength range 280-420 nm
Absorption cross sectiond have been obtained by personal communication from Fang Liu (April 2014) together with the following remark:
"Please note that due to experimental factors the absolute cross sections may have uncertainties on the order of a factor of 2" |
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