When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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DATAFILE: | CH3CH=CH2C(O)O_Lin(2022)_299K_300-500nm.txt |
NAME: | methyl vinyl ketone oxide, MVKO |
FORMULA: | CH3CH=CH2C(O)O |
AUTHOR(YEAR): | Lin(2022) |
T: | 299K |
λ: | 300-500nm |
BIBLIOGRAPHY: |
Y.-H. Lin, K. Takahashi, and J. J.-M. Lin, "Absolute photodissociation cross sections of thermalized methyl vinyl ketone oxide and methacrolein oxide",
Phys. Chem. Chem. Phys. 24, 10439-10450 (2022);
DOI: 10.1039/d2cp00476c
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COMMENTS: | Synthesis of MVKO by photolysis at 352 nm of a 1,3-diiodo-but-2-ene precursor
Determination of the absolute photodissociation cross section σdiss at 352 nm by the laser depletion method, see
Y.-H.-Lin and J.J.-M. Lin, J. Chin. Chem. Soc. 69, 152-159 (2022); DOI: 10.1002/jccs.202100336
Scaling of the spectrum (absorbances vs. wavelength) published by
Caravan et al., "Direct kinetic measurements and theoretical predictions of an isoprene-derived Criegee intermediate", Proc. Natl. Acad. Sci. U.S.A., 117, 9733−9740 (2020); DOI: 10.1073/pnas.1916711117,
to σdiss yielded absolute absorption cross sections for MVKO
Data have been obtained by personal communication from Jim Jr-Min Lin (October 2022) |
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