When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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| DATAFILE: | CF2ClCHO_JPL-2010(2011)_298K_235-370nm(rec).txt |
| NAME: | chlorodifluoroacetaldehyde |
| FORMULA: | CF2ClCHO |
| AUTHOR(YEAR): | JPL-2010(2011) |
| T: | 298K |
| λ: | 235-370nm(rec) |
| BIBLIOGRAPHY: |
S.P. Sander, J. Abbatt, J. R. Barker, J. B. Burkholder, R. R. Friedl, D. M. Golden, R. E. Huie, C. E. Kolb, M. J. Kurylo, G. K. Moortgat, V. L. Orkin and P. H. Wine, "Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 17",
JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, 2011; http://jpldataeval.jpl.nasa.gov/
|
| COMMENTS: | JPL-2010 recommendation, adopting the earlier recommendation of
S.P. Sander, R.R. Friedl, D.M. Golden, M.J. Kurylo, G.K. Moortgat, H. Keller-Rudek, P.H. Wine, A.R. Ravishankara, C.E. Kolb, M.J. Molina, B.J. Finlayson-Pitts, R.E. Huie, V.L. Orkin, “Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies. Evaluation Number 15“, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, 2006; http://jpldataeval.jpl.nasa.gov/:
235-350 nm, mean of the data of H.G. Libuda, "Spektroskopische und kinetische Untersuchungen an halogenierten Carbonylverbindungen von atmosphärischem Interesse, PhD-Thesis, Univ. Wuppertal, Germany, 1992, and O.V. Rattigan, O. Wild, and R.A. Cox, "UV absorption cross-sections and atmospheric photolysis lifetimes of halogenated aldehydes," J. Photochem. Photobiol. A: Chem. 112, 1-7 (1998); DOI: 10.1016/S1010-6030(97)00250-5, 355-370 nm, data of O.V. Rattigan, O. Wild, and R.A. Cox, "UV absorption cross-sections and atmospheric photolysis lifetimes of halogenated aldehydes," J. Photochem. Photobiol. A: Chem. 112, 1-7 (1998); DOI: 10.1016/S1010-6030(97)00250-5. Temperature coefficients B for the parameterization ln σ(T) = ln σ(298 K) + B×(T-298) at T = 243-298 K of Rattigan et al. (1998): ------------------
λ 104 K
(nm) (K-1)
------------------
235 -29.0
240 -17.9
245 -13.5
250 -11.8
255 -10.7
260 -10.5
265 -10.4
270 -10.5
275 -9.96
280 -10.6
285 -10.2
290 -10.6
295 -9.54
300 -10.4
305 -7.09
310 -9.73
315 -8.32
320 -7.71
325 -5.02
330 -3.03
335 -2.83
340 -2.84
345 14.0
350 37.3
355 68.1
360 75.8
365 52.9
370 63.1 |
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