The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Organics (carbonyls) / Halogenated aldehydes / CF3C(O)Cl / Weibel(1995)_298K_254nm(max)

DATAFILE: CF3C(O)Cl_Weibel(1995)_298K_254nm(max).txt
NAME: trifluoroacetyl chloride
FORMULA: CF3C(O)Cl
AUTHOR(YEAR): Weibel(1995)
T: 298K
λ: 254nm(max)
BIBLIOGRAPHY: D.E. Weibel, G. A. Arguello, E. R. Staricco de, and E. H. Staricco, "Quantum yield in the gas phase photolysis of perfluoroacetyl chloride: a comparison with related compounds", J. Photochem. Photobiol. A: Chem. 86, 27-31 (1995); DOI: 10.1016/1010-6030(94)03920-P
COMMENTS: The UV spectrum of CF3C(O)CI was obtained using a Shimadzu 260 UV spectrophotometer

The maximum absorption coefficient at 254 nm (17.8 ± 0.2) L mol-1 cm-1 was converted to absorption cross section using factor 3.8235×10-21

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