The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Organics (carbonyls) / Halogenated aldehydes / COCl2 / IUPAC(2008)_298K_184.4-242.4nm(rec)

DATAFILE: COCl2_IUPAC(2008)_298K_184.4-242.4nm(rec).txt
NAME: phosgene, carbonyl dichloride
FORMULA: COCl2
AUTHOR(YEAR): IUPAC(2008)
T: 298K
λ: 184.4-242.4nm(rec)
BIBLIOGRAPHY: R. Atkinson, D.L. Baulch, R.A. Cox, J.N. Crowley, R.F. Hampson, R.G. Hynes, M.E. Jenkin, M.J. Rossi, J. Troe, and T.J. Wallington, "Evaluated kinetic and photochemical data for atmospheric chemistry: Volume IV - gas phase reactions of organic halogen species", Atmos. Chem. Phys. 8, 4141-4496 (2008); DOI: 10.5194/acp-8-4141-2008
COMMENTS: IUPAC(2008) recommendation:

The preferred values of the absorption cross sections are those reported by

D. Gillotay, P.C. Simon, and L. Dierickx, "Ultraviolet absorption cross-sections of some carbonyl compounds and their temperature dependence," Aeronomica Acta A 368, 1-15 (1993)

The spectrum is a continuum; the values listed are averaged over 500 cm-1 intervals

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