The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013


Cross Sections / Organics (carbonyls) / Halogenated aldehydes / COCl2 / JPL-2010(2011)_294-298K_168.10-305.36nm(rec)

DATAFILE: COCl2_JPL-2010(2011)_294-298K_168.10-305.36nm(rec).txt
NAME: phosgene, carbonyl dichloride
FORMULA: COCl2
AUTHOR(YEAR): JPL-2010(2011)
T: 294-298K
λ: 168.10-305.36nm(rec)
BIBLIOGRAPHY: S.P. Sander, J. Abbatt, J. R. Barker, J. B. Burkholder, R. R. Friedl, D. M. Golden, R. E. Huie, C. E. Kolb, M. J. Kurylo, G. K. Moortgat, V. L. Orkin and P. H. Wine, "Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 17", JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, 2011; http://jpldataeval.jpl.nasa.gov/
COMMENTS: JPL-2010 recommendation, adopting the earlier recommendation of

S.P. Sander, R.R. Friedl, D.M. Golden, M.J. Kurylo, G.K. Moortgat, H. Keller-Rudek, P.H. Wine, A.R. Ravishankara, C.E. Kolb, M.J. Molina, B.J. Finlayson-Pitts, R.E. Huie, V.L. Orkin, “Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies. Evaluation Number 15“, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, 2006; http://jpldataeval.jpl.nasa.gov/ :

168.10-173.15 nm, data of

D. Gillotay, P.C. Simon, and L. Dierickx, "Ultraviolet absorption cross-sections of some carbonyl compounds and their temperature dependence," Aeronomica Acta A 368, 1-15 (1993),

174.65-182.56 nm, mean of the data of

D. Gillotay, P.C. Simon, and L. Dierickx, "Ultraviolet absorption cross-sections of some carbonyl compounds and their temperature dependence," Aeronomica Acta A 368, 1-15 (1993), and

M. Jäger, H. Heydtmann, and C. Zetzsch, "Vacuum ultraviolet spectrum and quantum yield of the 193 nm photolysis of phosgene," Chem. Phys. Lett. 263, 817-821 (1996); DOI: 10.1016/S0009-2614(96)01278-X ,

184.35-199.00 nm, mean of the data of

C.C. Chou, G. Crescentini, H. Vera-Ruiz, W.S. Smith, and F.S. Rowland, "Stratospheric photochemistry of CF2O, CClFO, and CCl2O," presented at the 173rd American Chemical Meeting, New Orleans, LA, 1977,

D. Gillotay, P.C. Simon, and L. Dierickx, "Ultraviolet absorption cross-sections of some carbonyl compounds and their temperature dependence," Aeronomica Acta A 368, 1-15 (1993), and

M. Jäger, H. Heydtmann, and C. Zetzsch, "Vacuum ultraviolet spectrum and quantum yield of the 193 nm photolysis of phosgene," Chem. Phys. Lett. 263, 817-821 (1996); DOI: 10.1016/S0009-2614(96)01278-X ,

201.01-218.59 nm, mean of the data of

C.C. Chou, G. Crescentini, H. Vera-Ruiz, W.S. Smith, and F.S. Rowland, "Stratospheric photochemistry of CF2O, CClFO, and CCl2O," presented at the 173rd American Chemical Meeting, New Orleans, LA, 1977,

D. Gillotay, P.C. Simon, and L. Dierickx, "Ultraviolet absorption cross-sections of some carbonyl compounds and their temperature dependence," Aeronomica Acta A 368, 1-15 (1993),

R. Meller, D. Boglu, and G.K. Moortgat, "UV spectra of several halogenated carbonyl compounds and FTIR studies on the degradation of CF3COCl, HCFC-123 and HCFC-134a", in: Kinetics and Mechanisms for the reactions of halogenated organic compounds in the troposphere. STEP-HALOCSIDE/AFEAS Workshop, Dublin, Eire, 1991, pp. 110-115, and

M. Jäger, H. Heydtmann, and C. Zetzsch, "Vacuum ultraviolet spectrum and quantum yield of the 193 nm photolysis of phosgene," Chem. Phys. Lett. 263, 817-821 (1996); DOI: 10.1016/S0009-2614(96)01278-X ,

221.00-226.00 nm, mean of the data of

C.C. Chou, G. Crescentini, H. Vera-Ruiz, W.S. Smith, and F.S. Rowland, "Stratospheric photochemistry of CF2O, CClFO, and CCl2O," presented at the 173rd American Chemical Meeting, New Orleans, LA, 1977,

D. Gillotay, P.C. Simon, and L. Dierickx, "Ultraviolet absorption cross-sections of some carbonyl compounds and their temperature dependence," Aeronomica Acta A 368, 1-15 (1993),

R. Meller, D. Boglu, and G.K. Moortgat, "UV spectra of several halogenated carbonyl compounds and FTIR studies on the degradation of CF3COCl, HCFC-123 and HCFC-134a", in: Kinetics and Mechanisms for the reactions of halogenated organic compounds in the troposphere. STEP-HALOCSIDE/AFEAS Workshop, Dublin, Eire, 1991, pp. 110-115,

228.58-305.36 nm, mean of the data of

D. Gillotay, P.C. Simon, and L. Dierickx, "Ultraviolet absorption cross-sections of some carbonyl compounds and their temperature dependence," Aeronomica Acta A 368, 1-15 (1993), and

R. Meller, D. Boglu, and G.K. Moortgat, "UV spectra of several halogenated carbonyl compounds and FTIR studies on the degradation of CF3COCl, HCFC-123 and HCFC-134a", in: Kinetics and Mechanisms for the reactions of halogenated organic compounds in the troposphere. STEP-HALOCSIDE/AFEAS Workshop, Dublin, Eire, 1991, pp. 110-115

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