The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Organics (carbonyls) / Halogenated aldehydes / COFCl / IUPAC(2008)_298K_186.0-231.2nm(rec)

DATAFILE: COFCl_IUPAC(2008)_298K_186.0-231.2nm(rec).txt
NAME: fluorochlorophosgene, carbonyl chloro-fluoride
FORMULA: COFCl
AUTHOR(YEAR): IUPAC(2008)
T: 298K
λ: 186.0-231.2nm(rec)
BIBLIOGRAPHY: R. Atkinson, D.L. Baulch, R.A. Cox, J.N. Crowley, R.F. Hampson, R.G. Hynes, M.E. Jenkin, M.J. Rossi, J. Troe, and T.J. Wallington, "Evaluated kinetic and photochemical data for atmospheric chemistry: Volume IV - gas phase reactions of organic halogen species", Atmos. Chem. Phys. 8, 4141-4496 (2008); DOI: 10.5194/acp-8-4141-2008
COMMENTS: IUPAC(2008) recommendation:

The preferred values of the absorption cross-sections are those reported by

C.C. Chou, G. Crescentini, H. Vera-Ruiz, W.S. Smith, and F.S. Rowland, "Stratospheric photochemistry of CF2O, CClFO, and CCl2O," presented at the 173rd American Chemical Meeting, New Orleans, LA, 1977 (unpublished),

over the wavelength range 186 to 199 nm and those reported by

A. Nölle, H. Heydtmann, R. Meller, and G.K. Moortgat, "Temperature dependent UV absorption spectra of carbonyl chloro-fluoride," Geophys. Res. Lett. 20, 707-710 (1993); DOI: 10.1029/93GL00248 ,

at longer wavelengths

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