The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Organics (carbonyls) / Halogenated aldehydes / COHCl / IUPAC(2008)_298K_236.1-318.7nm(rec)

DATAFILE: COHCl_IUPAC(2008)_298K_236.1-318.7nm(rec).txt
NAME: formyl chloride
FORMULA: COHCl
AUTHOR(YEAR): IUPAC(2008)
T: 298K
λ: 236.1-318.7nm(rec)
BIBLIOGRAPHY: R. Atkinson, D.L. Baulch, R.A. Cox, J.N. Crowley, R.F. Hampson, R.G. Hynes, M.E. Jenkin, M.J. Rossi, J. Troe, and T.J. Wallington, "Evaluated kinetic and photochemical data for atmospheric chemistry: Volume IV - gas phase reactions of organic halogen species", Atmos. Chem. Phys. 8, 4141-4496 (2008); DOI: 10.5194/acp-8-4141-2008
COMMENTS: IUPAC(2008) recommendation:

The preferred values of the absorption cross-sections at 298 K are those reported by

H.G. Libuda, F. Zabel, E.H. Fink, and K.H. Becker, "Formyl chloride: UV absorption cross sections and rate constants for the reactions with Cl and OH," J. Phys. Chem. 94, 5860-5865 (1990); DOI: 10.1021/j100378a047.

These are the values of the absorption cross-sections at the absorption maxima and were measured at a spectral resolution of 0.7 nm

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