The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Organics (carbonyls) / Ketones,ketenes / CH3C(O)CH=CH2 / Fahr(1993)_298K_160.0-260.0nm

DATAFILE: CH3C(O)CH=CH2_Fahr(1993)_298K_160.0-260.0nm.txt
NAME: methyl vinyl ketone, MVK
FORMULA: CH3C(O)CH=CH2
AUTHOR(YEAR): Fahr(1993)
T: 298K
λ: 160.0-260.0nm
BIBLIOGRAPHY: A. Fahr, W. Braun, and A. H. Laufer, "Photolysis of methyl vinyl ketone at 193 nm: Quantum yield determinations of methyl and vinyl radicals", J. Phys. Chem. 97, 1502-1506 (1993); DOI: 10.1021/j100110a1007
COMMENTS: The absorption cross sections were determined employing a one meter, single beam, vacuum monochromator provided with interchangeable vacuum UV and UV photomultipliers, a deuterium light source, analog to digital circuitry, a computer controlled stepping motor drive for wavelength control, and computerized data acquisition

The absorption spectrum depicted in Fig. 1 has been digitized

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