When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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| DATAFILE: | FC(O)O_Maricq(1993)_295K_470-829nm.txt |
| NAME: | fluoroformyloxyl radical |
| FORMULA: | FC(O)O |
| AUTHOR(YEAR): | Maricq(1993) |
| T: | 295K |
| λ: | 470-829nm |
| BIBLIOGRAPHY: |
M.M. Maricq, J.J. Szente, G.A. Khitrov, and J.S. Francisco, "Temperature dependent kinetics of the formation and self-reactions of FC(O)O2 and FC(O)O radicals",
J. Chem. Phys. 98, 9522-9531 (1993);
DOI: 10.1063/1.464383
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| COMMENTS: | Absorption measurements using F2/CO/O2 gas mixtures and a flash photolysis/time resolved UV-vis spectrometer system.
Absorption cross sections at 0.5-nm intervals have been obtained by personal communication from M.Matti Maricq (April 1999).
In a preliminary study a qualitative spectrum (absorbance vs. wavenumber) has been analyzed and assigned to the B 2A1 - X 2B2 system by
M.M. Maricq, J.J. Szente , Z. Li, and J.S. Francisco, "Visible absorption spectroscopy of the B 2A1 - X 2B2 system transition of fluoroformyloxyl radical, FC(O)O," J. Chem. Phys. 98, 784-790 (1993); DOI: 10.1063/1.464241
The kinetics of FC(O)O reactions with a number of atmospherically important species and other reactants has studied by laser flash photolysys/transient UV-visible spectroscopy by
M.M. Maricq, J.J. Szente, T.S. Dibble, and J.S. Francisco, "Atmospheric chemical kinetics of FC(O)O," J. Phys. Chem. 98, 12294-12309 (1994); DOI: 10.1021/j100098a027 |
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