When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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DATAFILE: | CH3C(O)CH2O2_Cox(1990)_298K_225-380nm(W-rev).txt |
NAME: | acetonylperoxy radical |
FORMULA: | CH3C(O)CH2O2 |
AUTHOR(YEAR): | Cox(1990) |
T: | 298K |
λ: | 225-380nm(W-rev) |
BIBLIOGRAPHY: |
R.A. Cox, J. Munk, O.J. Nielsen, P. Pagsberg, and P. Ratajczak, "Ultraviolet absorption spectra and kinetics of acetonyl and acetonylperoxy radicals",
Chem. Phys. Lett. 173, 206-210 (1990);
DOI: 10.1016/0009-2614(90)80079-S
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COMMENTS: | Pulse radiolysis (SF6/CH3C(O)CH3/O2 mixtures)/transient UV absorption technique W-rev = Wallington review Absorption cross sections have been read from Fig. 1 by T.J. Wallington, P. Dagaut, and M.J. Kurylo, "Ultraviolet absorption cross sections and reaction kinetics and mechanisms for peroxy radicals in the gas phase," Chem. Rev. 92, 667-710 (1992); DOI: 10.1021/cr00012a008 Correction: Value at 260 nm: 1.46×10-18 cm2 molecule-1 instead of 1.86×10-18 cm2 molecule-1 |
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