The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Peroxy radicals / Alkylperoxy+Cl / CHCl2O2 / Catoire(1996)_298K_205-290nm(Gaussian fit)

DATAFILE: CHCl2O2_Catoire(1996)_298K_205-290nm(Gaussian fit).txt
NAME: dichloromethylperoxy radical
FORMULA: CHCl2O2
AUTHOR(YEAR): Catoire(1996)
T: 298K
λ: 205-290nm(Gaussian fit)
BIBLIOGRAPHY: V. Catoire, R. Lesclaux, W.F. Schneider, and T.J. Wallington, "Kinetics and mechanism of the self-reactions of CCl3O2 and CHCl2O2 radicals and their reactions with HO2", J. Phys. Chem. 100, 14356-14371 (1996); DOI: 10.1021/jp960572z
COMMENTS: Flash photolysis of Cl2/CH2Cl2/O2/N2 mixtures coupled with absorption spectrometry

Calibration of the spectrum against the CH3O2 spectrum

Gaussian fit to the measured data points (Fig. 1 digitized)

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