The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Peroxy radicals / Alkylperoxy / CH3O2 / Roehl(1996)_298K_210,225,240nm

DATAFILE: CH3O2_Roehl(1996)_298K_210,225,240nm.txt
NAME: methylperoxy radical
FORMULA: CH3O2
AUTHOR(YEAR): Roehl(1996)
T: 298K
λ: 210,225,240nm
BIBLIOGRAPHY: C.M. Roehl, D. Bauer, and G.K. Moortgat, "Absorption spectrum and kinetics of the acetylperoxy radical", J. Phys. Chem. 100, 4038-4047 (1996); DOI: 10.1021/jp9526298
COMMENTS: CH3O2 evolved as secondary products of the rapid self reaction of acetylperoxy radicals generated by laser flash photolysis of Cl2, using the 351 nm XeF line of an excimer laser, in the presence of CH3CHO and O2
Absorption cross sections of CH3O2 as used for kinetic simulations of the reactions of the acetylperoxy radical

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