The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Peroxy radicals / Hydroxy-,methoxyalkylperoxy / CH2(OH)O2 / Burrows(1989)_298K_215-280nm

DATAFILE: CH2(OH)O2_Burrows(1989)_298K_215-280nm.txt
NAME: hydroxymethylperoxy radical
FORMULA: CH2(OH)O2
AUTHOR(YEAR): Burrows(1989)
T: 298K
λ: 215-280nm
BIBLIOGRAPHY: J.P. Burrows, G.K. Moortgat, G.S. Tyndall, R.A. Cox, M.E. Jenkin, G.D. Hayman, and B. Veyret, "Kinetics and mechanism of the photooxidation of formaldehyde. 2. Molecular modulation studies", J. Phys. Chem. 93, 2375-2382 (1989); DOI: 10.1021/j100343a034
COMMENTS: The transient species in the photooxidation of formaldehyde in air has been investigated by using the technique of modulated photolysis-long path kinetic spectroscopy

Data as quoted in the review article of

T.J. Wallington, P. Dagaut, and M.J. Kurylo, "Ultraviolet absorption cross sections and reaction kinetics and mechanisms for peroxy radicals in the gas phase", Chem. Rev. 92, 667-710 (1992); DOI: 10.1021/cr00012a008

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