The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Silicon compounds / (CH3)5Si2H / Kerst(1998)_298K_176-243nm

DATAFILE: (CH3)5Si2H_Kerst(1998)_298K_176-243nm.txt
NAME: pentamethyldisilane
FORMULA: (CH3)5Si2H
AUTHOR(YEAR): Kerst(1998)
T: 298K
λ: 176-243nm
BIBLIOGRAPHY: C. Kerst, I. Lein, and P. Potzinger,, " Gas-phase photolysis of pentamethyldisilane at 206 nm,", J. Photochem. Photobiol. A: Chem. 113, 9-21 (1998); DOI: 10.1016/S1010-6030(97)00305-5
COMMENTS: No experimental details given. Presumably the same as for the absorption measurements of hexamethyldisilane (single beam apparatus incorporating a stabilized deuterium lamp, a vacuum UV monochromator, and a photomultiplier) by

S. Patzer, R.N. Arthur, P. Potzinger, and H.G. Wagner, Photolysis of hexamethyldisilane at 206 nm, J. Photochem. Photobiol. A: Chem, 110, 221-227 (1997); DOI: 10.1016/S1010-6030(97)00198-6

The data points for the absorption cross sections shown in Fig. 1 (logarithmic scaling of the σ axis) have been digitized, and the wavelengths have been rounded

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